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21Sc44.96

Element 21, a transition metal

Scandium

A light, rare metal that Mendeleev predicted before anyone found it, now used to strengthen the aluminum in bike frames and baseball bats.

At a glance

Symbol
Sc
Atomic number
21
Average atomic mass
44.96
Group
3
Period
4
Family
transition metal
Electron configuration
[Ar] 3d¹ 4s²
Electronegativity
1.36
Common ions
Sc³⁺

On the table

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Period 4, group 3. The other transition metals are tinted, and every cell opens its own article.

Electrons and bonding

Scandium has 21 electrons, one for every proton, so the atom carries no charge. Below are the same 21 electrons written two ways.

Simple form: electrons per shell

Sc
shell 12shell 28shell 39shell 42
Counting outward from the nucleus: 2, 8, 9, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹ 4s²

Short form: [Ar] 3d¹ 4s², where [Ar] stands for the 18 electrons argon already has.

That list runs by shell. In the order the subshells fill it reads [Ar] 4s² 3d¹, because a subshell fills by its energy, not by its shell number.

3d¹↑
4s²↑↓
The boxes hold the electrons beyond [Ar]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 3 here is 3s² 3p⁶ 3d¹, and 2 + 6 + 1 is 9.

Scandium sits in period 4 and has 4 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones scandium can lose, gain or share, so they are the ones that decide what it bonds with.

Scandium gives up its two 4s electrons and its single 3d electron to form Sc³⁺, the only ion it commonly makes, so it behaves more like aluminum than like a typical transition metal.

Properties

State at 25 °C
solid
What it looks like
soft, silvery-white metal that yellows slightly in air
Melting point
1541 °C
Boiling point
2836 °C
Density
2.99 g/cm³

Where it is found

More common in the crust than lead, but spread so thinly that there are few ores worth mining. It is recovered mostly as a byproduct of processing other ores, in China, Russia and the Philippines.

Discovery and name

Lars Fredrik Nilson found it in 1879 in the minerals euxenite and gadolinite and named it after Scandinavia. Per Teodor Cleve soon pointed out that it was the eka-boron Mendeleev had predicted in 1871, with the atomic mass and properties he had described.

What it is used for

A little scandium makes aluminum alloys stronger for bicycle frames, baseball bats and aircraft parts. Scandium iodide goes into metal-halide lamps that light stadiums and film sets with daylight-like light, and scandium-doped zirconia is used in solid oxide fuel cells.

In compounds

Sc₂O₃scandium oxideScI₃scandium iodide, in stadium lampsScCl₃scandium chlorideScF₃scandium fluoride