All practice pages/Interatomic theory/Elements

31Ga69.72

Element 31, a post-transition metal

Gallium

A metal that melts in your hand, predicted by Mendeleev before it was found, and a key ingredient of the blue LED.

At a glance

Symbol
Ga
Atomic number
31
Average atomic mass
69.72
Group
13
Period
4
Family
post-transition metal
Electron configuration
[Ar] 3d¹⁰ 4s² 4p¹
Valence electrons
3
Electronegativity
1.81
Common ions
Ga³⁺

On the table

Periodic table with Gallium highlighted123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 4, group 13. The other post-transition metals are tinted, and every cell opens its own article.

Electrons and bonding

Ga

Three valence electrons, which gallium gives up to form Ga³⁺. With arsenic and nitrogen it forms the covalent semiconductors gallium arsenide and gallium nitride.

Properties

State at 25 °C
solid
What it looks like
soft, silvery metal that melts just above room temperature
Melting point
29.8 °C
Boiling point
2204 °C
Density
5.91 g/cm³
Odd fact
it expands when it freezes, like water, and stays liquid from 30 °C to above 2200 °C

Where it is found

Never mined for itself. It is recovered in small amounts while bauxite is processed into aluminum and while zinc ores are refined, and China produces nearly all of it.

Discovery and name

Paul-Émile Lecoq de Boisbaudran spotted two new violet lines in the spectrum of a zinc ore in 1875 and isolated the metal the same year. It matched Mendeleev's predicted eka-aluminium so closely, down to its density once it was remeasured, that the periodic table won wide acceptance. He named it after Gallia, Latin for France; some suspected a pun on his own name, since gallus means rooster, le coq in French.

What it is used for

Almost all goes into semiconductors: gallium arsenide chips in phones and in solar cells for satellites, and gallium nitride in blue and white LEDs, laser diodes and compact phone chargers. Galinstan, a gallium-indium-tin alloy that is liquid at room temperature, replaces mercury in some thermometers.

In compounds

GaAsgallium arsenide, a semiconductorGaNgallium nitride, blue LEDsGa₂O₃gallium oxideGaCl₃gallium chloride

Handle with care

Not very toxic, but liquid gallium attacks aluminum and makes it brittle, so it is kept away from aluminum parts.