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63Eu151.96

Element 63, a lanthanide

Europium

The red glow of old color televisions, and part of the hidden glow that protects euro banknotes from counterfeiters.

At a glance

Symbol
Eu
Atomic number
63
Average atomic mass
151.96
Group
none; it sits in the lanthanide row below the table
Period
6
Family
lanthanide
Electron configuration
[Xe] 4f⁷ 6s²
Electronegativity
not measured
Common ions
Eu³⁺ and Eu²⁺

On the table

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Period 6, in the lanthanide row set below the main table. The other lanthanides are tinted, and every cell opens its own article.

Electrons and bonding

Europium has 63 electrons, one for every proton, so the atom carries no charge. Below are the same 63 electrons written two ways.

Simple form: electrons per shell

Eu
shell 12shell 28shell 318shell 425shell 58shell 62
Counting outward from the nucleus: 2, 8, 18, 25, 8, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f⁷ 5s² 5p⁶ 6s²

Short form: [Xe] 4f⁷ 6s², where [Xe] stands for the 54 electrons xenon already has.

That list runs by shell. In the order the subshells fill it reads [Xe] 6s² 4f⁷, because a subshell fills by its energy, not by its shell number.

4f⁷↑↑↑↑↑↑↑
6s²↑↓
The boxes hold the electrons beyond [Xe]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 4 here is 4s² 4p⁶ 4d¹⁰ 4f⁷, and 2 + 6 + 10 + 7 is 25.

Europium sits in period 6 and has 6 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones europium can lose, gain or share, so they are the ones that decide what it bonds with.

Like the other lanthanides, it gives up three electrons to form the Eu³⁺ ion in most of its compounds.

Properties

State at 25 °C
solid
What it looks like
soft, silvery metal that tarnishes quickly; the most reactive lanthanide
Melting point
822 °C
Boiling point
1529 °C
Density
5.24 g/cm³

Where it is found

One of the less common rare earths, found in bastnäsite and monazite, mostly mined in China.

Discovery and name

Eugène-Anatole Demarçay separated it in 1901 after noticing unexplained lines in the spectra of samarium samples, and named it after Europe.

What it is used for

Europium phosphors glow red and blue in fluorescent lamps, LEDs and old tube televisions, whose red dots contained europium. Europium compounds that glow under ultraviolet light are used as security marks, including on euro banknotes.

In compounds

Eu₂O₃europium oxide, red phosphorEuCl₃europium chlorideEuSeuropium sulfide