All practice pages/Interatomic theory/Elements

29Cu63.55

Element 29, a transition metal

Copper

The first metal people worked, the wire in nearly every electric cable, and the reason the Statue of Liberty is green.

At a glance

Symbol
Cu
Atomic number
29
Average atomic mass
63.55
Group
11
Period
4
Family
transition metal
Electron configuration
[Ar] 3d¹⁰ 4s¹
Electronegativity
1.90
Common ions
Cu²⁺ (blue in water) and Cu⁺

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 4, group 11. The other transition metals are tinted, and every cell opens its own article.

Electrons and bonding

Copper has 29 electrons, one for every proton, so the atom carries no charge. Below are the same 29 electrons written two ways.

Simple form: electrons per shell

Cu
shell 12shell 28shell 318shell 41
Counting outward from the nucleus: 2, 8, 18, 1. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s¹

Short form: [Ar] 3d¹⁰ 4s¹, where [Ar] stands for the 18 electrons argon already has.

That list runs by shell. In the order the subshells fill it reads [Ar] 4s¹ 3d¹⁰, because a subshell fills by its energy, not by its shell number.

3d¹⁰↑↓↑↓↑↓↑↓↑↓
4s¹↑
The boxes hold the electrons beyond [Ar]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 3 here is 3s² 3p⁶ 3d¹⁰, and 2 + 6 + 10 is 18.

Copper sits in period 4 and has 4 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 1 electron. Those are the ones copper can lose, gain or share, so they are the ones that decide what it bonds with.

Like other transition metals, copper loses its outer s electrons, and often some d electrons as well, to form positive ions, and it can form more than one kind.

Properties

State at 25 °C
solid
What it looks like
reddish-orange, shiny metal that dulls to brown and eventually green
Melting point
1084.6 °C
Boiling point
2562 °C
Density
8.93 g/cm³
Flame test
blue-green

Where it is found

Sometimes found as pure native copper, but mostly mined from sulfide ores such as chalcopyrite (CuFeS₂); Chile is the largest producer. Your body needs a little copper for enzymes, and octopuses, crabs and snails carry oxygen with a copper protein, hemocyanin, which turns their blood blue.

Discovery and name

Used for about 10,000 years; copper beads from the Middle East date to around 9000 BCE, and mixing it with tin to make bronze began the Bronze Age. The Romans got much of their copper from Cyprus and called it aes Cyprium, Cyprus metal, later cuprum, which gives the symbol Cu.

What it is used for

Most goes into electrical wiring, motors and electronics, because only silver conducts electricity better. It also makes water pipes, roofing and heat exchangers, and alloys: brass with zinc and bronze with tin. Copper surfaces kill many bacteria, and the green patina on old copper roofs and statues protects the metal beneath.

In compounds

CuSO₄·5H₂Ocopper(II) sulfate, blue crystalsCu₂Ocopper(I) oxide, redCuOcopper(II) oxide, blackCu₂(OH)₂CO₃malachite, and the green patinaCuFeS₂chalcopyrite ore