All practice pages/Interatomic theory/Elements

61Pm[145]

Element 61, a lanthanide

Promethium

The only lanthanide with no stable isotopes, so scarce in nature that it was finally found among the products of nuclear fission.

At a glance

Symbol
Pm
Atomic number
61
Mass number of its longest-lived isotope
[145]
Group
none; it sits in the lanthanide row below the table
Period
6
Family
lanthanide
Electron configuration
[Xe] 4f⁵ 6s²
Electronegativity
not measured
Common ions
Pm³⁺
Isotopes
none are stable; ¹⁴⁵Pm lasts longest, with a half-life of about 18 years, and ¹⁴⁷Pm is the most used

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 6, in the lanthanide row set below the main table. The other lanthanides are tinted, and every cell opens its own article.

Electrons and bonding

Promethium has 61 electrons, one for every proton, so the atom carries no charge. Below are the same 61 electrons written two ways.

Simple form: electrons per shell

Pm
shell 12shell 28shell 318shell 423shell 58shell 62
Counting outward from the nucleus: 2, 8, 18, 23, 8, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f⁵ 5s² 5p⁶ 6s²

Short form: [Xe] 4f⁵ 6s², where [Xe] stands for the 54 electrons xenon already has.

That list runs by shell. In the order the subshells fill it reads [Xe] 6s² 4f⁵, because a subshell fills by its energy, not by its shell number.

4f⁵↑↑↑↑↑
6s²↑↓
The boxes hold the electrons beyond [Xe]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 4 here is 4s² 4p⁶ 4d¹⁰ 4f⁵, and 2 + 6 + 10 + 5 is 23.

Promethium sits in period 6 and has 6 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones promethium can lose, gain or share, so they are the ones that decide what it bonds with.

Like the other lanthanides, it gives up three electrons to form the Pm³⁺ ion in most of its compounds.

Properties

State at 25 °C
solid
What it looks like
silvery, radioactive metal
Melting point
1042 °C
Boiling point
3000 °C
Density
7.26 g/cm³

Where it is found

Almost none exists in nature: only about half a kilogram is thought to exist in the Earth's crust at any moment, made by the rare spontaneous splitting of uranium atoms. Nearly all of it is made in nuclear reactors.

Discovery and name

Its place in the table sat empty for decades while several claimed discoveries fell apart. Jacob Marinsky, Lawrence Glendenin and Charles Coryell identified it in 1945 at Oak Ridge, among the products of uranium fission. Coryell's wife, Grace Mary, suggested naming it after Prometheus, who stole fire from the gods.

What it is used for

Promethium-147 once powered nuclear batteries for pacemakers and made luminous paint for watch dials. Today it is used mainly in research and in gauges that measure the thickness of materials.

In compounds

Pm₂O₃promethium oxidePmCl₃promethium chloride

Handle with care

Radioactive. It is handled behind shielding and must be kept out of the body.