All practice pages/Interatomic theory/Elements

62Sm150.36

Element 62, a lanthanide

Samarium

The first element named, indirectly, after a person, and half of the magnets that keep working when things get hot.

At a glance

Symbol
Sm
Atomic number
62
Average atomic mass
150.36
Group
none; it sits in the lanthanide row below the table
Period
6
Family
lanthanide
Electron configuration
[Xe] 4f⁶ 6s²
Electronegativity
1.17
Common ions
Sm³⁺, and also Sm²⁺

On the table

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Period 6, in the lanthanide row set below the main table. The other lanthanides are tinted, and every cell opens its own article.

Electrons and bonding

Samarium has 62 electrons, one for every proton, so the atom carries no charge. Below are the same 62 electrons written two ways.

Simple form: electrons per shell

Sm
shell 12shell 28shell 318shell 424shell 58shell 62
Counting outward from the nucleus: 2, 8, 18, 24, 8, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f⁶ 5s² 5p⁶ 6s²

Short form: [Xe] 4f⁶ 6s², where [Xe] stands for the 54 electrons xenon already has.

That list runs by shell. In the order the subshells fill it reads [Xe] 6s² 4f⁶, because a subshell fills by its energy, not by its shell number.

4f⁶↑↑↑↑↑↑
6s²↑↓
The boxes hold the electrons beyond [Xe]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 4 here is 4s² 4p⁶ 4d¹⁰ 4f⁶, and 2 + 6 + 10 + 6 is 24.

Samarium sits in period 6 and has 6 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones samarium can lose, gain or share, so they are the ones that decide what it bonds with.

Like the other lanthanides, it gives up three electrons to form the Sm³⁺ ion in most of its compounds.

Properties

State at 25 °C
solid
What it looks like
silvery metal that tarnishes slowly in air
Melting point
1074 °C
Boiling point
1794 °C
Density
7.52 g/cm³

Where it is found

Found in monazite and bastnäsite, mostly mined in China.

Discovery and name

Paul-Émile Lecoq de Boisbaudran found it in 1879 in the mineral samarskite, which had been named after Vasili Samarsky-Bykhovets, a Russian mining engineer who supplied the samples. That makes samarium the first element named, by way of a mineral, after a person.

What it is used for

Samarium-cobalt magnets hold their strength at high temperatures and resist corrosion, so they are used in aerospace and military equipment and in some electric guitar pickups. Samarium-153 eases bone pain from cancer, samarium absorbs neutrons in reactor control rods, and samarium(II) iodide is a tool for organic chemists.

In compounds

SmCo₅samarium-cobalt magnetSm₂O₃samarium oxideSmI₂samarium(II) iodide