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55Cs132.91

Element 55, an alkali metal

Cesium

A soft, pale gold metal that melts on a hot day, explodes in water, and defines the length of a second.

At a glance

Symbol
Cs
Atomic number
55
Average atomic mass
132.91
Group
1
Period
6
Family
alkali metal
Electron configuration
[Xe] 6s¹
Valence electrons
1
Electronegativity
0.79
Common ions
Cs⁺

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 6, group 1. The other alkali metals are tinted, and every cell opens its own article.

Electrons and bonding

Cesium has 55 electrons, one for every proton, so the atom carries no charge. Below are the same 55 electrons written two ways.

Simple form: electrons per shell

Cs
shell 12shell 28shell 318shell 418shell 58shell 61
Counting outward from the nucleus: 2, 8, 18, 18, 8, 1. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 6s¹

Short form: [Xe] 6s¹, where [Xe] stands for the 54 electrons xenon already has.

6s¹↑
The boxes hold the electrons beyond [Xe]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 3 here is 3s² 3p⁶ 3d¹⁰, and 2 + 6 + 10 is 18.

Cesium sits in period 6 and has 6 shells. The period number counts the shells.

What that means for bonding

Cs

The outer shell holds 1 electron. Those are the ones cesium can lose, gain or share, so they are the ones that decide what it bonds with. For a main-group element the group number gives that count: group 1 means 1.

One valence electron, which cesium gives up easily to form the Cs⁺ ion. Like the other alkali metals, it reacts with water.

Properties

State at 25 °C
solid
What it looks like
soft, pale gold metal that melts just above room temperature
Melting point
28.4 °C
Boiling point
671 °C
Density
1.93 g/cm³
Flame test
blue-violet

Where it is found

Rare, found mostly in the mineral pollucite. The largest known deposit is at Bernic Lake in Manitoba, Canada, with others in Zimbabwe and Australia.

Discovery and name

Robert Bunsen and Gustav Kirchhoff found it in 1860 in mineral water from Dürkheim, Germany, as two bright blue lines in their spectroscope, making it the first element discovered by spectroscopy. They named it from the Latin caesius, sky blue.

What it is used for

The second is defined by cesium-133: exactly 9,192,631,770 cycles of the radiation that flips a cesium atom between two energy states, counted by cesium atomic clocks. Cesium formate brines are dense drilling fluids for deep oil and gas wells, cesium goes into photoelectric cells, and radioactive cesium-137 treats cancer and gauges thickness in industry.

In compounds

CsClcesium chlorideHCOOCscesium formate, a drilling fluidCs₂CO₃cesium carbonateCsOHcesium hydroxide, a very strong base

Handle with care

Explodes on contact with water and catches fire in air. Radioactive cesium-137, released by the Chernobyl and Fukushima accidents, is a long-lasting contaminant.