All practice pages/Interatomic theory/Elements

26Fe55.85

Element 26, a transition metal

Iron

The metal of civilization since the Iron Age, the heart of our planet, and the atom that carries oxygen in your blood.

At a glance

Symbol
Fe
Atomic number
26
Average atomic mass
55.85
Group
8
Period
4
Family
transition metal
Electron configuration
[Ar] 3d⁶ 4s²
Electronegativity
1.83
Common ions
Fe²⁺ (iron(II)) and Fe³⁺ (iron(III))
Isotopes
⁵⁶Fe (91.8%), with smaller amounts of ⁵⁴Fe, ⁵⁷Fe and ⁵⁸Fe

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 4, group 8. The other transition metals are tinted, and every cell opens its own article.

Electrons and bonding

Iron has 26 electrons, one for every proton, so the atom carries no charge. Below are the same 26 electrons written two ways.

Simple form: electrons per shell

Fe
shell 12shell 28shell 314shell 42
Counting outward from the nucleus: 2, 8, 14, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁶ 4s²

Short form: [Ar] 3d⁶ 4s², where [Ar] stands for the 18 electrons argon already has.

That list runs by shell. In the order the subshells fill it reads [Ar] 4s² 3d⁶, because a subshell fills by its energy, not by its shell number.

3d⁶↑↓↑↑↑↑
4s²↑↓
The boxes hold the electrons beyond [Ar]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 3 here is 3s² 3p⁶ 3d⁶, and 2 + 6 + 6 is 14.

Iron sits in period 4 and has 4 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones iron can lose, gain or share, so they are the ones that decide what it bonds with.

Iron gives up two electrons to form Fe²⁺ or three to form Fe³⁺. Having two common ions is why its compounds are named with Roman numerals, as in iron(III) oxide.

Properties

State at 25 °C
solid
What it looks like
shiny gray metal that rusts in moist air
Melting point
1538 °C
Boiling point
2861 °C
Density
7.87 g/cm³
Magnetic
yes; iron, cobalt and nickel are the metals that are strongly magnetic at room temperature

Where it is found

By mass, the most abundant element in the Earth as a whole, because the core is mostly iron and nickel, and the fourth most abundant in the crust, about 5%. It is mined as hematite (Fe₂O₃) and magnetite (Fe₃O₄), above all in Australia and Brazil. Some meteorites are almost pure iron-nickel metal.

Discovery and name

Known since ancient times. The earliest iron objects were hammered from meteorites, and smelting iron from ore became widespread around 1200 BCE, beginning the Iron Age. The name is Old English; the symbol Fe comes from its Latin name, ferrum.

What it is used for

Steel, which is iron with a little carbon, is by far the most used metal: buildings, bridges, cars, ships, pipes, cans and tools. Cast iron makes pans and engine blocks. Iron oxides color paint, bricks and pottery, and iron is an essential nutrient, since hemoglobin in red blood cells uses it to carry oxygen.

In compounds

Fe₂O₃iron(III) oxide, hematite and rustFe₃O₄magnetite, a natural magnetFeSO₄iron(II) sulfate, iron supplementsFeS₂pyrite, fool's goldFeCl₃iron(III) chloride, etches circuit boardsFe₄[Fe(CN)₆]₃Prussian blue